NEST Seminar: Stefano Veronesi  

Pisa - 19.04.2018 - NEST Seminar: Stefano Veronesi

Date and time: Thursday , April 19, 2018 - 15.00
Venue: NEST seminar room

Speaker: Dr. Stefano Veronesi, NEST CNR Nano, Pisa , Italy

Title: A sensitive calorimetric tecnique to study energy (heat) exchange at the nano-scale

Every time a chemical reaction occurs, an energy exchange between reactants and environment exists, which is defined as the enthalpy of the reaction. In the last decades, research has resulted in an increasing number of devices at the micro- or nano-scale. Sensors, catalyzers, and energy storage systems are more and more developed as nano-devices which represent the building blocks for commercial "macroscopic" objects. A general method for the direct evaluation of the energy balance of such systems is not available at present. Calorimetry is a powerful tool to investigate energy exchange, but it usually needs macroscopic sample quantities. Here we report on the development of an original experimental setup able to detect temperature variations as low as 10 mK in a sample of ⁓ 10 ng using a thermometer device having physical dimensions of 5x5 mm2. The technique has been utilized to measure the enthalpy release during the adsorption process of H2 on a titanium decorated monolayer graphene. The sensitivity of these thermometers is high enough to detect a hydrogen uptake of ⁓ 10-10 moles, corresponding to ⁓ 0.2 ng, with an enthalpy release of about 23 μJ. The experimental setup allows, in perspective, the scalability to even smaller sizes.

Host: Fabio Taddei & Stefan Heun


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